MALLINCKRODT BAKER, INC -- HYDROGEN PEROXIDE SOLUTION 30%, 5170  -- 6810-00N088027
<pre>=====================  Product Identification  =====================

Product ID:HYDROGEN PEROXIDE SOLUTION 30%, 5170
MSDS Date:09/08/1997
FSC:6810
NIIN:00N088027
=== Responsible Party ===
Company Name:MALLINCKRODT BAKER, INC
Address:222 RED SCHOOL LANE
City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Info Phone Num:800-582-2537
Emergency Phone Num:908-859-2151;800-424-9300(CHEMTREC)
CAGE:HO851
=== Contractor Identification ===
Company Name:MALLINCKRODT BAKER INC
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:800-582-2537
CAGE:HO851
Company Name:MALLINCKRODT BAKER,  INC.
Address:222 RED SCHOOL LANE
Box:City:PHILLIPSBURG
State:NJ
ZIP:08865
Country:US
Phone:800-582-2537
CAGE:70829

=============  Composition/Information on Ingredients  =============

Ingred Name:HYDROGEN PEROXIDE, 30% (SARA 302)
CAS:7722-84-1
RTECS #:MX0899000
Fraction by Wt: 29-32%
OSHA PEL:1 PPM
ACGIH TLV:1 PPM

Ingred Name:WATER
CAS:7732-18-5
RTECS #:ZC0110000
Fraction by Wt: 68-71%
OSHA PEL:N/K 
ACGIH TLV:N/K 

Ingred Name:CNDTNS TO AVOID: A STRONG OXIDIZER, REACTS VIOLENTLY UPON
    CONT W/MANY ORG SUBSTANCES, PARTICULARLY TEXTILE & (ING 4)
RTECS #:9999999ZZ

Ingred Name:ING 3: PAPER. AVOID LIGHT & KEEP IN CLOSED BUT VENTED
    CONTAINER TO PREVENT EVAPORATION (CONC) & CONTAMINATION. (ING 5)
RTECS #:9999999ZZ

Ingred Name:ING 4: AVOID EXCESSIVE HEAT AND CONTACT WITH COMBUSTIBLE OR
    ORGANIC MATERIALS. LIGHT AND INCOMPATIBLE.
RTECS #:9999999ZZ

Ingred Name:FIRST AID PROC: THORO CLEAN SHOES BEFORE REUSE. IF ALLOWED
    TO DRY ON CLTHG, EVAP LEADS TO CONC & INCRD POSS OF (ING 7)
RTECS #:9999999ZZ

Ingred Name:ING 6: IGNIT. EYES: IMMED FLUSH W/PLENTY OF WATER FOR AT
    LEAST 15 MIN, LIFTING LOWER & UPPER EYELIDS OCCAS. GET (ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7: MED ATTN IMMED. NOTE TO MD: PULM EDEMA MAY BE
    DELAYED FOR 24-72 HRS; KEEP UNDER OBSERVATION. GASTRIC (ING 9)
RTECS #:9999999ZZ

Ingred Name:ING 8: LAVAGE MAY BE NEC IF SWALLOWED. ANALYSIS OF BODY
    FLUIDS (PARTICULARLY GASTRIC ASPIRATES) USING TITANIUM (ING 10)
RTECS #:9999999ZZ

Ingred Name:ING 9: CHLORIDE REACTION, IF DONE IMMEDIATELY, WILL REVEAL
    PEROXIDES.
RTECS #:9999999ZZ

Ingred Name:SPILL PROC: DYKED AREA UNTIL PEROXIDE DECOMPOSES FOLLOWED
    BY DISCHARGE INTO SUITABLE TREATMENT SYS. MAY BE NEUT (ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11: W/SODIUM METABISULFITE/SODIUM SULFITE AFTER
    DILUTING TO 5-10% PEROXIDE. DO NOT FLUSH UNDILUTED MATL TO (ING 13)
RTECS #:9999999ZZ

Ingred Name:ING 12: SEWER. THIS OXIDIZING MATL CAN INCR FLAMMABILITY OF
    ADJACENT COMBUST MATLS. EMPTY CONTRS SHOULD BE (ING 14)
RTECS #:9999999ZZ

Ingred Name:ING 13: RINSED WITH WATER BEFORE DISCARDING.
RTECS #:9999999ZZ

Ingred Name:WASTE DISP METH: DILUTE W/WATER & FLUSH TO SEWER IF LOC
    ORDINANCES ALLOW, OTHERWISE, WHATEVER CANNOT BE SAVED (ING 16)
RTECS #:9999999ZZ

Ingred Name:ING 15: FOR RECOVERY/RECYCLING SHOULD BE MANAGED IN APPROP
    & APPRVD WASTE DISP FACILITY. PROCESSING, USE/CONTAM (ING 17)
RTECS #:9999999ZZ

Ingred Name:ING 16: OF THIS PROD MAY CHANGE WASTE MANAGEMENT OPTIONS.
    STATE & LOC DISP REGS MAY DIFFER FROM FED DISP REGS. (ING 18)
RTECS #:9999999ZZ

Ingred Name:ING 17: DISPOSE OF CONTAINER AND UNUSED CONTENTS IN
    ACCORDANCE WITH FEDERAL, STATE AND LOCAL REQUIREMENTS.
RTECS #:9999999ZZ

Ingred Name:OTHER PREC: RAPID DECOMP W/GENERATION OF LGE QTYS OF OXYGEN
    GAS & HIGH PRESS. RINSE EMPTY CONTRS THORO W/CLEAN (ING 20)
RTECS #:9999999ZZ

Ingred Name:ING 19: WATER. GLASS, POLYETHYLENE, STAINLESS STEEL &
    ALUMINUM ARE REC MATLS FOR STOR CONTRS. CONTRS OF THIS (ING 21)
RTECS #:9999999ZZ

Ingred Name:ING 20: MATL MAY BE HAZ WHEN EMPTY SINCE THEY RETAIN PROD
    RESIDUES (VAPS, LIQ); OBSERVE ALL WARNINGS & PREC LISTED.
RTECS #:9999999ZZ

Ingred Name:VENT: BECAUSE IT CAN CTL EMISSIONS OF CONTAMINANT AT ITS
    SOURCE, PREVENTING DISPERSION OF IT INTO GEN WORK AREA.(ING 23)
RTECS #:9999999ZZ

Ingred Name:ING 22: PLEASE REFER TO ACGIH DOCUMENT, INDUS VENT, A
    MANUAL OF RECOMMENDED PRACTICES, MOST RECENT EDITION, FOR DETAILS.
RTECS #:9999999ZZ

Ingred Name:EYE PROTECTION: AND FULL LENGTH FACESHIELD .
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INHAL: VAPS ARE CORR &
    IRRITATING TO RESP TRACT. INHAL OF MIST MAY BURN MUC MEMB OF NOSE &
    THROAT. IN SEV CASES, EXPOS MAY RSLT IN PULM EDEMA & DEATH. INGEST:
    CORR & IRRITATING TO MOUTH, THROAT , & ABDOMEN. LGE DOSES MAY CAUSE
    SYMPS OF ABDOM PAIN, VOMIT, & DIARR AS WELL AS BLISTERING/TISS
    (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ: DESTRUCTION. STOM DISTENTION (DUE TO
    RAPID LIBERATION OF OXYGEN), & RISK OF STOM PERFORATION, CONVLS,
    PUML EDEMA, COMA, POSS CEREBRAL EDEMA (FLUID ON BRAIN), & DEATH ARE
    POSS. SKIN: CORR. SY MPS OF REDNESS, PAIN, & SEV BURNS CAN OCCUR.
    EYES: VAPS ARE VERY CORR & IRRITATING. SYMPS INCL PAIN, REDNESS &
    (SUP DAT)
Medical Cond Aggravated by Exposure:PERSONS WITH PREEXISTING SKIN
    DISORDERS OR EYE PROBLEMS OR IMPAIRED RESPIRATORY FUNCTION MAY BE
    MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE.

=======================  First Aid Measures  =======================

First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF
    BRTHG IS DFCLT, GIVE OXYGEN. GET MED ATTN IMMED. INGEST: IF
    SWALLOWED, DO NOT INDUCE VOMIT. GIVE LGE QTYS OF WATER. NEVER GIVE
    ANYTHING BY  MOUTH TO AN UNCON PERS. GET MED ATTN IMMED. SKIN:
    IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN WHILE REMOVING
    CONTAM CLTHG & SHOES. GET MED ATTN IMMED. WASH CLTHG BEFORE REUSE.
    (ING 6)

=====================  Fire Fighting Measures  =====================

Flash Point:NOT COMBUSTIBLE
Extinguishing Media:WATER SPRAY MAY BE USED TO EXTING SURROUNDING FIRE
    & COOL EXPOSED CONTRS. WATER SPRAY WILL REDUCE FUME & IRRITANT
    GASES.
Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE
    EQUIPMENT .
Unusual Fire/Explosion Hazard:NOT COMBUST, BUT A STRONG OXIDIZER & ITS
    HEAT OF RXN W/REDUCING AGENTS/COMBUSTS MAY CAUSE IGNIT. INCRS FLAM
    OF COMBUST, ORG & READILY OXIDIZABLE MATLS.(SUP DAT)

==================  Accidental Release Measures  ==================

Spill Release Procedures:CAUTION! CAUSTIC MATL. CAUSES FIRE W/ORG MATL.
    VENT AREA. WEAR APPROP PERS PROT EQUIP AS SPECIFIED. CONTAIN &
    RECOVER LIQ WHEN POSS. DO NOT RETURN SPILLED MATL TO ORIGINAL
    CONTR. LARGER SPILLS: DILUTE  W/LGE AMT OF WATER & HOLD IN POND
    OR(ING 11)
Neutralizing Agent:SODIUM METABISULFITE OR SODIUM SULFITE.

======================	Handling and Storage  ======================

Handling and Storage Precautions:STORE IN COOL (<35C), WELL-VENTD DARK
    AREA SEPARATED FROM COMBUST MATLS, REDUCING AGENTS, STRONG BASES,
    ORGS. DO NOT STORE ON WOODEN SHELVES/FLOORS.
Other Precautions:SUGGEST ROTATION OF STOCK. CONTRS MUST BE VENTED, BUT
    CHECK PERIODICALLY FOR BULGING CONTRS WHICH CAN BURST FROM PRESS.
    PROTECT CONTRS FROM PHYSICAL DMG, CONTAM, HEAT & INCOMPATIBLES.
    CONTAM FROM ANY  SOURCE (DUST, METALS) MAY CAUSE (ING 19)

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:IF THE EXPOSURE LIMIT IS EXCEEDED, WEAR A NIOSH
    APPROVED SUPPLIED AIR, FULL-FACEPIECE RESPIRATOR, AIRLINED HOOD, OR
    FULL-FACEPIECE SELF-CONTAINED BREATHING APPARATUS. THIS SUBSTANCE
    HAS UNKNOWN WARNIN G PROPERTIES.
Ventilation:SYS OF LOC &/OR GEN EXHST IS REC TO KEEP EMPLOYEES EXPOS
    BELOW AIRBORNE EXPOS LIMS. LOC EXHST VENT IS GEN PREF (ING 22)
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGG (ING 24)
Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER .
    WEAR IMPERVIOUS PROT CLTHG, INCL BOOTS, LAB COAT, APRON/COVERALLS.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
EXPLO HAZ: CONT W/OXIDIZABLE SUBSTANCES MAY CAUSE EXTREMELY VIOLENT
    COMBUST. DRYING OF CONC HYDROGEN PEROXIDE ON CLTHG/OTHER COMBUST
    MATLS MAY CAUSE FIRE/EXPLO. SEALED CONTRS MAY RUPTURE WHEN HEATED. 
    MATLS TO AVOID: CON W/READILY FLAM MATLS. EFTS OF OVEREXP: BLURRED
    VISION. SPLASHES CAN CAUSE PERM TISS DESTRUCTION.

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:226F,108C
Melt/Freeze Pt:M.P/F.P Text:-13F,-25C
Vapor Pres:25 @ 30C
Vapor Density:1.17
Spec Gravity:1.1
pH:3.3
Evaporation Rate &amp; Reference:<1 (BUTYL ACETATE=1)
Solubility in Water:INFINITELY SOLUBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID WITH SLIGHT ACRID ODOR
Percent Volatiles by Volume:100

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
HEAT, REDUCING AGENTS, ORG MATLS, DIRT, ALKALIS, RUST, & MANY METALS.
    SPONT COMBUST MAY OCCUR ON STANDING IN (SUP DAT)
Stability Condition to Avoid:NORM STABLE IF UNCONTAM, BUT SLOWLY
    DECOMPOSES TO RELEASE OXYGEN. UNSTABLE W/HEAT, MAY RSLT IN
    DANGEROUS PRESS. (ING 3)
Hazardous Decomposition Products:DECOMPOSES TO WATER & OXYGEN W/RAPID
    HEAT RELEASE. USE VENTED CONTRS. SOLUTION CAN DECOMPOSE VIOLENTLY
    UPON HEATING.

====================  Disposal Considerations  ====================

Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING
    SHOULD BE HANDLED AS HAZ WASTE & SENT TO RCRA APPRVD WASTE
    FACILITY. PROCESSING, USE/CONTAM OF THIS PROD MAY CHANGE WASTE
    MANAGEMENT OPTIONS. STATE & LO C DISP REGS MAY DIFFER FROM FED DISP
    REGS.(ING 15)

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