SYSCO CHEMICAL -- RELIANCE CLEAR AMMONIA, 4160511 -- 6810-00N084686
===================== Product Identification ===================== Product ID:RELIANCE CLEAR AMMONIA, 4160511 MSDS Date:07/01/1994 FSC:6810 NIIN:00N084686 === Responsible Party === Company Name:SYSCO CHEMICAL Address:1390 ENCLAVE PARKWAY City:HOUSTON State:TX ZIP:77077 Country:US Info Phone Num:713-584-1790 Emergency Phone Num:800-228-5635;800-424-9300(CHEMTREC) CAGE:SYSCO === Contractor Identification === Company Name:SYSCO CHEMICAL Address:1390 ENCLAVE PARKWAY Box:City:HOUSTON State:TX ZIP:77077 Country:US Phone:713-584-1790 CAGE:SYSCO ============= Composition/Information on Ingredients ============= Ingred Name:NO INGREDIENT FOR THIS FORMULATION_INGREDIENT ===================== Hazards Identification ===================== LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE:STRONGLY CORR TO ALL TISSUES ON EXPOS. INGEST:HARMFUL OR FATAL IF SWALLOWED. CORROSIVE. CAUSES SEVERE DAMAGE TO MOUTH, THROAT & STOMACH, LEADING TO ABDOMINAL PAIN, NAUSEA, VOMITING, COLLAPSE & P OSSIBLE DEATH. INHAL:VAPORS ARE EXTREMELY IRRITATING TO RESPIRATORY TRACT. DAMAGES AIRWAYS AND LUNGS. (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT Effects of Overexposure:HLTH HAZ:CORR EFTS INCL PULM EDEMA, BRONCHITIS, CHEM PNEUM & CHRONIC RESP DISEASE. EYE CONT:CAUSES SEV CHEM BURNS. SEVERELY CORR. MAY CAUSE PERM CORNEAL DMG INCL PERFORATION, ULCERATION & BLINDNESS. S KIN CONT:CAUSES SEV CHEM BURNS. CORROSIVE. CAN CAUSE SEV BURNS W/POSSIBLE BLISTERING & TISSUE DESTRUCTION. Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER. ======================= First Aid Measures ======================= First Aid:INGEST:DO NOT INDUCE VOMIT. IMMED DRINK LG QTY OF WATER. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERS. GET MED ATTN IMMED. INHAL:REMOVE TO FRESH AIR & GIVE ARTF RESP IF NOT BRTHG. FOR SEV CONT, GET IMME D MED ATTN. EYES:IMMED FLUSH W/PLENTY OF COOL RUNNING WATER. REMOVE CONTACT LENSES IF APPLIC & CONTINUE FLUSHING FOR AT LST 15 MINS, HOLDING LIDS APART TO ENSURE THORO RINSING OF ENTIRE EYE. (ING 3) ===================== Fire Fighting Measures ===================== Flash Point:NONE Lower Limits:16% Upper Limits:25% Extinguishing Media:IN INVOLVED IN A FIRE, USE CARBON DIOXIDE, DRY CHEMICAL OR WATER SPRAY. Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . USE WATER SPRAY TO KEEP FIRE-EXPOS CNTNRS COOL USE WATER FOG/SPRAY TO REMOVE GENERATED AMMONIA GAS FROM ATM. Unusual Fire/Explosion Hazard:AMMONIA GAS WILL BE LIBERATED AT ALL TEMPS, WHICH CAN BE EXPLO UNDER CONFINED SPACE CNDTNS. CONT BTWN THIS PROD & CONC MINERAL ACIDS WILL CAUSE INSTANT (SUPDAT) ================== Accidental Release Measures ================== Spill Release Procedures:SMALL SPILLS:MOP UP RESIDUE & RINSE AREA THOROUGHLY W/WATER. LARGE SPILLS:DIKE OR DAM SOIL. PUMP TO CONTAINERS OR SOAK UP ON INERT ABSORBENT. USE PERSONAL PROTECTIVE EQUIPMENT & STAY UPWIND OF SPILL. CONSIDERED BIODEGRADABLE. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:PROD IS A STRONGLY ALKALINE MATERIAL; HANDLE W/CARE, AS FOR ALL STRONG CHEMICALS. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. KEEP FROM FREEZING. Other Precautions:HANDLE EMPTY CNTNRS AS IF FULL, DUE TO PRESENCE OF RESIDUAL AMMONIA VAPS. STORE IN COOL, DRY, WELL-VENTED PLACE. KEEP AWAY FROM BLEACH & ACIDIC MATLS. OBSERVE LBL PRECS, USE PERSONAL PROT EQUIP. AVOID BRTHG VAPORS OF THIS PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:USE NIOSH APPROVED RESPIRATOR FOR HIGH VAPOR CONCENTRATIONS IN CONFINED AREAS. Ventilation:LOCAL EXHAUST VENTILATION MAY BE REQUIRED TO KEEP VAPORS W/IN EXPOSURE LIMITS. Protective Gloves:PVC/NEOPRENE GLOVES W/LONG GAUNTLET. Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS &(SUPDAT) Other Protective Equipment:ANSI APPRVD EYE WASH FOUNTAIN & DELUGE SHOWER . APRON REC; PVC, NEOPRENE/VINYL ACCEPTABLE. BOOTS REC TO (SUPDAT) Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health EXPLO HAZ:BOILING & POSS EXPLO. WASTE DISP METH:LOC AUTHS FOR ADDNL RESTRICTIONS. RCRA CLASS:NON-HAZ. RECYCLE CNTNR. EYE PROT:FULL LGTH FSHLD . OTHER PROT EQUIP:PROT SHOES & FEET WHEN USING PROD FOR FLOOR CLEANING. MATLS TO AVOID:GALVANIZED METALS. CONT W/STRONG ACIDS PRDCES EXOTHERMIC, POSSIBLY VIOLENT (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:212F,100C Decomp Temp:Decomp Text:928F,498C Spec Gravity:0.980 pH:11.5 Solubility in Water:COMPLETE Appearance and Odor:CLEAR COLORLESS LIQUID; PUNGENT AMMONIA ODOR. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES DO NOT MIX W/HOT WATER/CHLORINE BLEACH. AVOID CONT W/ACIDS OR ALKALIES, OXIDIZING MATLS, COPPER ALUMINUM, ZINC &(SUPDAT) Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER. Hazardous Decomposition Products:AMMONIA GAS & OXIDES OF NITROGEN. CHLORAMINES - FROM CONTACT W/HYPOCHLORITE BLEACH. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS . SM AMTS OF UNUSED PROD MAY BE FLUSHED SAFELY TO SANIT SEWER W/PLENTY OF WATER. CONT LOC WATER BOARD BEFORE FLUSHING LG AMTS. IF SOLIDIFIED, LG AMTS MAY BE DISP OF IN SANIT LANDFILL. CONT STATE/(SUPDAT) Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.