HUMMEL CHEMICAL COMP.INC. -- PHOSPHORUS,RED -- 6810-00D000505
===================== Product Identification ===================== Product ID:PHOSPHORUS,RED MSDS Date:01/01/1985 FSC:6810 NIIN:00D000505 === Responsible Party === Company Name:HUMMEL CHEMICAL COMP.INC. Emergency Phone Num:201-754-1800 CAGE:8A933 === Contractor Identification === Company Name:HUMMEL CHEMICAL COMP.INC. CAGE:8A933 ============= Composition/Information on Ingredients ============= Ingred Name:RED PHOSPHORUS(AMORPHOUS) CAS:7723-14-0 RTECS #:TH3495000 Fraction by Wt: 99.9% ACGIH TLV:UNSPECIFIED EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== Effects of Overexposure:IRRITATING TO EYES;OTHERWISE ESSENTIALLY HARMLESS & NON-TOXIC UNLESS CONTAM BY HIGHLY TOXIC YELL.P. ======================= First Aid Measures ======================= First Aid:EYES:FLUSH THOROUGHLY WITH WATER.SKIN:FLUSH W/WATER & SOAP.CAUTION:AVOID BRUSHING-FRICTION COULD IGNITE MATERIAL ON SKIN OR CLOTHING. ===================== Fire Fighting Measures ===================== Autoignition Temp:Autoignition Temp Text:395F Extinguishing Media:SAND,CO*2,DRY CHEMICAL,WATER SPRAY,FOAM Fire Fighting Procedures:AFTER EXTINGUISHING,PREVENT RE-IGNITION BY EXCLUDING AIR Unusual Fire/Explosion Hazard:HEAT CAN CAUSE REVERSION TO YELLOW PHOSPHORUS WHICH IS TOXIC & SPONTANEOUSLY FLAMM W/AIR;TOX.P OXIDE ================== Accidental Release Measures ================== Spill Release Procedures:COVER WITH INERT FILLER(SAND,CLAY,ETC)SHOVEL & SWEEP UP CAREFULLT FOR RECLAIM OR USE.REPEAT IF NECESSARY TO CLEAN UP LAST TRACES OF SPILL. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN COOL,DRY PLACE AWAY FROM HEAT OR FIRE HAZARD.KEEP SEPARATED FROM OXIDIZERS & ALKALIES.HANDLE CAREFULLY TO AVOID FRICTION OR DUSTING. Other Precautions:SEPARATE FROM ALL SOURCES OF IGNITION SUFFICIENTLY.DO NOT CO-LOAD WITH EXPLOSIVES,OXIDIZING MATERIALS,POISONS & CORROSIVE MATERIALS.WEAR GLOVES & LARGE FACE SHIELD.EXPLODES W/OXID.AGENT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:DUST MASK,NUISANCE DUST Ventilation:LOCAL EXHAUST(GENERAL ROOM VENTILATION)IS PREFERRED Protective Gloves:FIRE PROOF. Eye Protection:CHEM.SAFETY SPECTACLES Other Protective Equipment:FLARE PROOFED,FULL PROTECTIVE EQUIPMENT RECOMM.FOR PERSONNEL Supplemental Safety and Health ITEM IS CLASS 2 OF MIL-P-211C.SPECIAL FIRE FIGHTING PROCEDURES(CONTD)AIR CAN BE EXCLUDED BY KEEPING WET OR COVERING W/WET SANT OR FOAM,ETC;WEAR FLAME PROOFED FULL PROTECTIVE CLOTHING. ================== Physical/Chemical Properties ================== HCC:F8 Boiling Pt:B.P. Text:395F(IGNITE Vapor Pres:UNK Vapor Density:4.77 Spec Gravity:0.95 Solubility in Water:NEGLIGIBLE Appearance and Odor:RED SOLID,PUNGENT ODOR. Percent Volatiles by Volume:UNK ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS,CHLORATES,NITRATES,HALOGENS,STRONG ALK.HYDROXIDE Stability Condition to Avoid:EXPOSURE TO HEAT, SPARKS,FRICTION OR MECHANICAL SHOCK Hazardous Decomposition Products:AIR & H*2O LIBERATE PHOSPHORUS ACIDS & TOXIC,FLAM.PHOSPHINE ==================== Disposal Considerations ==================== Waste Disposal Methods:RECOVER 6 USE OR INCINERATE UNDER CAREFUL SUPERVISION IN EQUIPMENT DESIGNED TO HANDLE OXIDES OF PHOSPHORUS AS COMBUSTION PRODUCTS,ALL IN ACCORDANCE WITH STATE,FEDERAL & LOCAL REGULATIONS,ALL IN ACCORD ANCE WITH FEDERAL,STATE & LOCAL REGS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.