MALLINCKRODT BAKER INC -- SODIUM PHOSPHATE TRIBASIC, 7940 -- 6810-00N092122
===================== Product Identification ===================== Product ID:SODIUM PHOSPHATE TRIBASIC, 7940 MSDS Date:12/08/1996 FSC:6810 NIIN:00N092122 Status Code:A === Responsible Party === Company Name:MALLINCKRODT BAKER INC Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Info Phone Num:800-582-2537 Emergency Phone Num:908-859-2151;800-424-9300 Resp. Party Other MSDS Num.:SOPHT Chemtrec Ind/Phone:(800)424-9300 CAGE:70829 === Contractor Identification === Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM PHOSPHATE, TRIBASIC. LD50: (ORAL,RAT) 7.4 G/KG. CAS:7601-54-9 RTECS #:TC9490000 > Wt:98. EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:SODIUM HYDROXIDE CAS:1310-73-2 RTECS #:WB4900000 < Wt:2.5 OSHA PEL:2 MG/M3 ACGIH STEL:C2 MG/M3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE INGREDIENT 1 Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: CAUSTIC, IRRITANT DUST, MAY CAUSE BURNING/DISCOMFORT IN RESPIRATORY PASSAGES. COUGHING, SNEEZING & POSSIBLE PAIN ARE SYMPTOMS. INGEST: CAUSTIC ALKALINE ACTION W/POSSIBLE IRRITATION/BURNI NG OF MUCOUS MEMBRANE IN MOUTH & ESOPHAGUS. ABDOMINAL PAIN, STRICTURE, VOMITING & DIARRHEA MAY FOLLOW INGESTION OF APPRECIABLE AMOUNTS. SKIN CONT: CAUSTIC BURNS MAY OCCUR ON PROLONGED CONTACT W/MOIST SKIN. REDDENING, SORENESS OR POSSIBLE DAMAGE TO SKIN MAY OCCUR. EYE CONT: CORROSIVE. MAY CAUSE IRRITATION, REDNESS, PAIN, AND EYE DAMAGE. (EFTS OF OVEREXPOSURE) Effects of Overexposure:HLTH HAZS: CHRONIC: MAY SEQUESTER CALCIUM & CAUSE CALCIUM PHOSPHATE DEPOSITS IN THE KIDNEYS. CHRONIC INGESTION OR INHALATION MAY INDUCE SYSTEMIC PHOSPHOROUS POISONING. LIVER DAMAGE, KIDNEY DAMAGE, JAW /TOOTH ABNORMALITIES, BLOOD DISORDERS AND CARDIOVASCULAR EFFECTS CAN OCCUR. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISITING SKIN DISORDERS/EYE PROBLEMS, JAW/TOOTH ABNORMALITIES/IMPAIRED LIVER, KIDNEY OR RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. GET MED ATTN IMMED. INGEST: DO NOT INDUCE VOMIT. GIVE LG QTYS OF WATER. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERSON. GET MED ATTN IMMED. SKIN CONT: IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS WHILE REMOVING CONTAMD CLTHG & SHOES. GET MED ATTN IMMED. WASH CLTHG BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE REUSE. EYE CONT: IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS, LIFTING LOWER & UPPER EYELIDS OCCASNLY. GET MED ATTN IMMED. NOTE TO PHYS: PERFORM ENDOSCOPY (SUPDAT) ===================== Fire Fighting Measures ===================== Extinguishing Media:NOT CONSIDERED TO BE FIRE HAZARD. USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. ADDING WATER TO CAUSTIC SOLUTION GENERATES LARGE AMOUNTS OF HEAT. Fire Fighting Procedures:IN EVENT OF A FIRE, WEAR FULL PROTECTIVE CLOTHING AND NIOSH-APPROVED SELF-CONTAINED BREATHING APPARATUS WITH FULL FACEPIECE OPERATED IN THE PRESSURE DEMAND OR OTHER POSITIVE PRESSURE MODE. Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE AN EXPLOSION HAZARD. AIRBORNE EXPOS LIMITS: SODIUM HYDROXIDE: OSHA PEL: 2MG/M3 CEILING-ACGIH THRESHOLD LIMIT VALUE (TLV): 2 MG/M3 CEILING TRISODIUM PHOSPHATE: -AIHA WORKPLACE ENVI RONMENTAL EXPOSURE LIMIT: 5 MG/M3(15-MINUTE STEL). ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF LEAK/SPILL. KEEP UNNEC & UNPROTECTED PEOPLE AWAY FROM AREA OF SPILL. WEAR APPROP PERSONAL PROT EQUIP AS SPECIFIED IN SECTION 8 EXPOS CTLS/PERSONAL PROT. DO NOT FLUSH CAUSTIC RESIDUES TO SEWER. RESIDUES FROM SPILLS CAN BE DILUTED W/WATER. ABSORB NEUTRALIZED CAUSTIC RESIDUE ON CLAY, VERMICULITE/OTHER INERT SUBSTANCE & PACKAGE IN SUITABLE CNTNR FOR DISP. USE REGS (OTHER INFO) Neutralizing Agent:NEUTRALIZE W/DILUTE ACID SUCH AS ACETIC, HYDROCHLORIC OR SULFURIC. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP IN TIGHTLY CLSD CNTNR. PROTECT FROM PHYSICAL DMG. STORE IN COOL, DRY, VENTILATED AREA AWAY FROM SOURCES OF HEAT, MOISTURE & INCOMPATIBILITIES. ALWAYS ADD CAUSTIC TO WATER WHILE STIRRING; NEVER RE VERSE. Other Precautions:CNTNRS OF THIS MATL MAY BE HAZARDOUS WHEN EMPTY SINCE THEY RETAIN PROD RESIDUES (DUST, SOLIDS); OBSERVE ALL WARNINGS & PRECAUTIONS LISTED FOR PRODUCT. DO NOT GET IN EYES, ON SKIN, OR ON CLOTHING. DO N OT BREATHE DUST. KEEP CONTAINER CLOSED. USE ONLY WITH ADEQUATE VENTILATION. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOSURE LIMIT IS EXCEEDED, A NIOSH APPRVD FULL FACEPIECE RESP W/HIGH EFFICIENCY DUST/MIST FILTER MAY BE WORN UP TO 50 TIME EXPOS LIMIT/MAX USE CONC SPECIFIED BY APPROP REGULATORY AGENCY/RESP SUPPL IER, WHICHEVER IS LOWEST. FOR EMER/INSTANCES WHERE EXPOS LEVELS ARE NOT KNOWN, US NIOSH APPRVD FULL FACEPIECE POS-PRESS, AIR-SUPPLIED (OTHER INFO) Ventilation:SYS OF LOC AND/OR GEN EXHST IS REC TO KEEP EMPLOYEE EXPOS BELOW AIRBORNE EXPOS LIMTS. LOC EXHST VENT IS GEN PREFERRED BECAUSE IT CAN CTL (OTHER INFO) Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGS & FULL LENGTH FACESHIELD . Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER . WEAR IMPERVIOUS PROTECTIVE CLOTHING, INCL BOOTS, GLOVES, LAB COAT, APRON OR COVERALLS, AS APPROP, TO PREVENT SKIN CONTACT. Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health FIRST AID PROC: IN ALL CASES OF SUSPECTED SODIUM HYDROXIDE INGEST. IN CASES OF SEV ESOPHAGEAL CORR, USE OF THERAPEUTIC DOSES OF STEROIDS SHOULD BE CONSIDERED. GEN SUPPORTIVE MEASURES W/CONTINUAL MONIT ORING OF GAS EXCHANGE, ACID-BASE BALANCE, ELECTROYLTES, & FLUID INTAKE ARE ALSO REQD. PH:11.9(1% AQUEOUS SOLN). ================== Physical/Chemical Properties ================== Boiling Pt:=100.C, 212.F B.P. Text:LOSES 12 H*2O(DECOMP) Melt/Freeze Pt:=75.C, 167.F M.P/F.P Text:CA. Vapor Pres:NO INFO FOUND Spec Gravity:1.6 pH:SUPDAT Evaporation Rate & Reference:NO INFORMATION FOUND Solubility in Water:26 GM IN 100 GM @ 20C Appearance and Odor:TRANSPARENT, COLORLESS CRYSTALS. ODORLESS. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES REACTS VIOLENTLY WITH WATER AND ACIDS TO LIBERATE HEAT. Stability Condition to Avoid:STABLE UNDER ORDINARY CONDITIONS OF USE AND STORAGE. Hazardous Decomposition Products:PHOSPHORUS OXIDES MAY FORM WHEN HEATED TO DECOMPOSITION. =================== Toxicological Information =================== Toxicological Information:SODIUM PHOSPHATE TRIBASIC DODECAHYDRATE: ORAL RAT LD50: 7.4 G/KG. ANHYDROUS: INVESTIGATED AS A MUTAGEN. ===================== Ecological Information ===================== Ecological:ENVIRONMENTAL FATE: NO INFORMATION FOUND. EVNIRONMENTAL TOXICITY: NO INFORMATION FOUND. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING SHOULD BE MANAGED IN APPROP & APPRVD WASTE FACILITY. ALTHOUGH NOT LISTED RCRA HAZ WASTE, THIS MATL MAY EXHIBIT 1/MORE CHARACT OF HAZ WASTE & REQ APPROP ANALYSIS TO DETERM SPECIFIC DISP REQUIREMENTS. PROCESSING, USE/CONTAM OF PROD MAY CHANGE WASTE (OTHE R INFO) =================== MSDS Transport Information =================== Transport Information:NOT REGULATED. ===================== Regulatory Information ===================== SARA Title III Information:INGRED: SODIUM HYDROXIDE (1310-73-2): SARA 302, RQ-NO, TPQ-NO, SARA 313, LIST-YES, CHEMICAL CATG.-NO. SODIUM PHOSPHATE, TRIBASIC (7601-54-9): SARA 302, RQ-NO, TPQ-NO, SARA 313, LIST-NO, CHEMICAL CATG. -NO. SARA 311/312: ACUTE: YES. CHRONIC: YES. FIRE: NO. PRESSURE: NO. REACTIVITY: YES. Federal Regulatory Information:INGRED: SODIUM HYDROXIDE (1310-73-2): CERCLA-1000, RCRA-261.33-NO, TSCA 8(D)-NO. INGRED: SODIUM PHOSPHATE, TRIBASIC (7601-54-9): CERCLA-5000, RCRA 261.33-NO, TSCA 8(D)-NO. CHEMICAL WEAPONS CONVENTION: NO TSCA 12(B): NO. CDTA: NO. AUSTRALIAN HAZCHEM CODE: NO INFORMATION FOUND. POISON SCHEDULE: S5. State Regulatory Information:WHMIS: THIS MSDS HAS BEEN PREPARED ACCORDING TO HAZARD CRITERIA OF CONTROLLED PRODS REGS (CPR) AND MSDS CNTNS ALL INFO REQD BY CPR. OTHER INFO: NFPA RATINGS: HEALTH:3, FLAMMABILITY: 0, REACTIVITY: 2. PRODUCT USE: INDUSTRIAL CHEMICAL. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.