TERMINAL PACKAGING CORP -- AIRBRAKE ANTIFREEZE, HDAAHA  -- 6850-00N078251
<pre>=====================  Product Identification  =====================

Product ID:AIRBRAKE ANTIFREEZE, HDAAHA
MSDS Date:10/05/1990
FSC:6850
NIIN:00N078251
=== Responsible Party ===
Company Name:TERMINAL PACKAGING CORP
Address:2000 RIVER RD
City:COUNCIL BLUFFS
State:IA
ZIP:51501
Country:US
Info Phone Num:712-323-9802
Emergency Phone Num:800-424-9300 (CHEMTREC)
CAGE:0KDB2
=== Contractor Identification ===
Company Name:TERMINAL PACKAGING CORP
Address:2850 RIVER RD
Box:City:COUNCIL BLUFFS
State:IA
ZIP:51501
Country:US
Phone:712-323-9802
CAGE:0KDB2

=============  Composition/Information on Ingredients  =============

Ingred Name:METHANOL; (METHYL ALCOHOL) (SARA 313) (CERCLA)
CAS:67-56-1
RTECS #:PC1400000
Fraction by Wt: 33%
OSHA PEL:200 PPM, S
ACGIH TLV:200 PPM;250 STEL, S
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Ingred Name:ACETONE (SARA 313) (CERCLA). %:0.001 MAX.
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 0.001%
OSHA PEL:1000 PPM
ACGIH TLV:750 PPM;1000 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Ingred Name:ETHYLENE GLYCOL (SARA 313) (CERCLA)
CAS:107-21-1
RTECS #:KW2975000
Fraction by Wt: 1-3%
OSHA PEL:N/K 
ACGIH TLV:50 PPM, VAPOR, C
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB

Ingred Name:SUPDAT:LIFTING LOWER & UPPER LIDS OCCAS. GET MED ATTN AS
    SOON AS POSS. SKIN:REMOVE CONTAM CLTHG. WASH AFFECTED (ING 5)
RTECS #:9999999ZZ

Ingred Name:ING 4:AREA W/SOAP & WATER; APPLY SKIN LOTIONS. IF
    IRRITATION PERSISTS, GET MEDICAL ATTENTION.
RTECS #:9999999ZZ

Ingred Name:SPILL PROC:COMBUST CHAMBER. SPILLS IN SENSITIVE AREAS MAY
    BE DILUTED & FLUSHED TO GROUND W/WATER SPRAY. DO NOT (ING 7)
RTECS #:9999999ZZ

Ingred Name:ING 6:FLUSH TO SEWER/OTHER CONFINED SPACE. SPILLS OF 5,000
    LBS/MORE MUST BE REPORTED TO THE NRC (800-424-8802) (ING 8)
RTECS #:9999999ZZ

Ingred Name:ING 7:PURSUANT TO CERCLA. WARN OCCUPANTS OF DOWNWIND AREAS.
RTECS #:9999999ZZ

Ingred Name:WASTE DISP METH:DISTILLATION PROCS. RCRA
    REQUIREMENTS:METHANOL IS ASSIGNED HAZ WASTE NUMBER OF U154 UNDER
    3001. (ING 10)
RTECS #:9999999ZZ

Ingred Name:ING 9:IT IS CONSIDERED A TOXIC WASTE.
RTECS #:9999999ZZ

Ingred Name:OTHER PREC:& VISUAL FUNCTIONS, LIVER & KIDNEY SYSTEMS.
    PROVIDE SUITABLE TRAINING TO THOSE WORKING W/METHANOL. (ING 12)
RTECS #:9999999ZZ

Ingred Name:ING 11:MONITOR THE WORKPLACE. KEEP RECORDS.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:NO    IARC:NO	OSHA:NO
Health Hazards Acute and Chronic:METHANOL IS POIS, NARC CHEM THAT CAN
    AFFECT BODY THRU INHAL, INGEST & PERHAPS PRLNG/RPTD SKIN CONT.
    ABSORPTION BY INHAL/INGEST IS RAPID & EXCRETION IS MUCH SLOWER THAN
    FOR ETHYL ALCOHOL, RESULTING IN  DELAYED EFT/COMPOUNDING OF EFTS BY
    RPTDEXPOS. IT IS IMPORTANT TO BE AWARE THAT AFTER INGEST/INHAL,
    (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:INITIAL SYMPS MAY BE ONLY THAT OF MILD
    INTOX, BUT MAY BECOME SEV AFTER 12-18 HRS. TOX EFTS ARE EXERTED
    UPON CNS, ESP OPTIC NERVE. INGEST CAN PRDCE BLINDNESS; 100-250 ML
    CAN BE FATAL. SYMPS OF  OVEREXP INCL DIZZ, VISUAL IMPAIRMENT, NAUS,
    RESP FAILURE, MUSCULAR INCOORD & NARCOS. PRLNG/RPTD SKIN CONT MAY
    (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:INGEST:GET MED ATTN IMMED. INDUCE VOMIT W/1 TBSP OF IPECAC/BY
    TOUCHING BACK OF THROAT (ONLY IF CONSCIOUS). ONCE VOMIT HAS
    OCCURRED, HAVE PATIENT DRINK MILK, WATER/SOLN OF SODIUM BICARBONATE
    IN WATER ( 1 HEAPING TBSP PER QUART). INHAL:REMOVEVICTIM TO FRESH
    AIR AT ONCE. RESTORE &/OR SUPPORT BRTHG AS REQD. KEEP VICTIM WARM &
    AT REST. GET MED ATTN AS SOON AS POSS. PVNT EXPOS TO METHANOL FOR 7
    (SUPDAT)

=====================  Fire Fighting Measures  =====================

Flash Point Method:CC
Flash Point:60.0F,15.6C
Lower Limits:6.7%
Upper Limits:36.5%
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, ALCOHOL FOAM & WATER
    MIST OR FOG. USE A BLANKETING EFFECT TO SMOTHER FIRE.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA & FULL PROTECTIVE
    EQUIPMENT .
Unusual Fire/Explosion Hazard:MODERATE EXPLOSION HAZARD & DANGEROUS
    FIRE HAZARD WHEN EXPOSED TO HEAT, SPARKS OR FLAMES & CAN REACT
    VIGOROUSLY W/OXIDIZING AGENTS.

==================  Accidental Release Measures  ==================

Spill Release Procedures:REMOVE ALL IGNIT SOURCES. PROVIDE ADEQ VENT.
    SM QTYS MAY BE ABSORBED ON PAPER TOWELS. EVAPORATE IN SAFE PLACE
    (SUCH AS FUME HOOD). BURN PAPER IN APPRVD INCIN/OPEN PIT AWAY FROM
    BLDGS & PEOPLE. LG QTYS  CAN BE COLLECTED & ATOMIZED IN SUITABLE
    (ING 6)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:FLAMM LIQ. GROUND & ELECTRICALLY
    INTERCONNECT CNTNRS FOR TRANSFER. USE SPARKPROOF TOOLS. NO SMOKING
    IN AREA OF USE/STOR. AVOID CONTACT W/EYES.
Other Precautions:AVOID PRLNG/RPTD BRTHG OF VAP/CONT W/SKIN. DO NOT
    INGEST! STORE IN WELL-VENTED, FIREPROOF AREA, AWAY FROM SOURCES OF
    HEAT, OPEN FLAME & IGNIT. PROVIDE PREPLACEMENT MED EXAMS FOR
    INDUSTRIALLY EXPOS WOR KERS, W/EMPHASIS ON NEUROLOGICAL(ING 11)

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:ANY NIOSH APPROVED AIR-SUPPLIED RESPIRATOR OR
    SELF-CONTAINED BREATHING APPARATUS. ONLY NIOSH APPROVED EQUIPMENT
    SHOULD BE USED.
Ventilation:LOC EXHST:TO MEET TLV REQUIREMENTS; 100 LFM MIN SHOULD BE
    USED WHERE VAP EXPOS IS LIKELY. MECH (GEN):CONTROLS (SUPDAT)
Protective Gloves:RUBBER GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS &(SUPDAT)
Other Protective Equipment:ANSI APPROVED EYE WASH FOUNTAIN & DELUGE
    SHOWER . IMPERVIOUS APRONS & BOOTS WHERE SPLASHING CAN OCCUR.
Work Hygienic Practices:CONTACT LENSES SHOULD NOT BE WORN WHILE
    HANDLING METHANOL.
Supplemental Safety and Health
% VOLAT:100(WT). EFTS OF OVEREXP:CAUSE DERM, ERYTHEMA, SCALING & POSS
    SYSTEMIC EFTS. TOX DATA:INHAL:8600 MG/M3=LACRIM; COUGH; OTHER
    CHANGES TO LUNGS, THORAX/RESP. VENT:MUST BE SPARKPROOF &
    EXPLO-PROOF . EYE PROT:FULL LGTH FSHLD . FIRST AID PROC:DAYS.
    EYES:WASH IMMED W/RUNNING WATER FOR AT LST 15 MINS, (ING 4)

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:181F,83C
Melt/Freeze Pt:M.P/F.P Text:144F,62C
Vapor Pres:97 @ 68F
Vapor Density:1.1
Spec Gravity:0.807 (H*2O=1)
Evaporation Rate &amp; Reference:5.9 (BUTYL ACETATE=1)
Solubility in Water:TOTALLY MISCIBLE
Appearance and Odor:CLEAR, COLORLESS LIQUID W/CHARACTERISTIC PUNGENT
    ALCOHOL ODOR.
Percent Volatiles by Volume:SUPDAT

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZING AGENTS SUCH AS NITRATES, PERCHLORATES OR SULFURIC
    ACID.
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAMES, OXIDIZING
    CONDITIONS.
Hazardous Decomposition Products:TOXIC GASES & VAPORS (I.E., CARBON
    MONOXIDE, FORMALDEHYDE) MAY BE RELEASED IN A METHANOL FIRE.

====================  Disposal Considerations  ====================

Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS .
    ABSORB IN VERMICULITE, DRY SAND, EARTH/SIMILAR MATL & DISP IN
    SECURED SANIT LANDFILL. ATOMIZE IN SUITABLE COMBUST CHAMBER; DISP
    OF VIA LICENSED WASTE S OLV DISP COMPANY/RECLAIM VIA FILTRATION&
    (ING 9)

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