MALLINCKRODT BAKER, INC -- ACETIC ACID GLACIAL, 2504 -- 6810-00N086665
===================== Product Identification ===================== Product ID:ACETIC ACID GLACIAL, 2504 MSDS Date:09/08/1997 FSC:6810 NIIN:00N086665 === Responsible Party === Company Name:MALLINCKRODT BAKER, INC Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Info Phone Num:800-582-2537 Emergency Phone Num:908-859-2151;800-424-9300(CHEMTREC) CAGE:HO851 === Contractor Identification === Company Name:MALLINCKRODT BAKER INC Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:HO851 Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:ACETIC ACID (CERCLA) CAS:64-19-7 RTECS #:AF1225000 Fraction by Wt: 100% OSHA PEL:10 PPM ACGIH TLV:10 PPM/15 STEL EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:EFTS OF OVEREXP: CHRONIC: REPEATED/PROLONGED EXPOS MAY CAUSE DARKENING OF SKIN, EROSION OF EXPOSED FRONT TEETH, (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: & CHRONIC INFLAMMATION OF THE NOSE, THROAT, AND BRONCHIAL TUBES. RTECS #:9999999ZZ Ingred Name:FIRST AID PROC: EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, LIFTING LOWER AND UPPER (ING 5) RTECS #:9999999ZZ Ingred Name:ING 4: EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION IMMEDIATELY. RTECS #:9999999ZZ Ingred Name:SPILL PROC: & PLACE IN CHEM WASTE CONTR. USE NON-SPKG TOOLS & EQUIP. DO NOT USE COMBUST MATLS, SUCH AS SAWDUST. (ING 7) RTECS #:9999999ZZ Ingred Name:ING 6: DO NOT FLUSH TO SEWER! US REGS (CERCLA) REQUIRE REPORTING SPILLS & RELEASES TO SOIL, WATER & AIR IN (ING 8) RTECS #:9999999ZZ Ingred Name:ING 7: EXCESS OF REPORTABLE QTYS. THE TOLL FREE NUMBER FOR US COAST GUARD NATIONAL RESPONSE CENTER IS (800) 424-8802. RTECS #:9999999ZZ Ingred Name:WASTE DISP METH: DISPOSE OF CONTAINER AND UNUSED PRODUCT IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REQUIREMENTS. RTECS #:9999999ZZ Ingred Name:OTHER PREC: STORE ABOVE 63F (17C). CONTAINERS MAY BE HAZARDOUS WHEN EMPTY SINCE THEY RETAIN PRODUCT RESIDUES (ING 11) RTECS #:9999999ZZ Ingred Name:ING 10: (VAPORS, LIQUID); OBSERVE ALL WARNINGS AND PRECAUTIONS LISTED FOR THE PRODUCT. RTECS #:9999999ZZ Ingred Name:RESP PROT: EXPOSURE LEVELS ARE NOT KNOWN, USE A FULL-FACEPIECE POSITIVE-PRESSURE, AIR-SUPPLIED RESPIRATOR. (ING 13) RTECS #:9999999ZZ Ingred Name:ING 12: WARNING: AIR PURIFYING RESPIRATORS DO NOT PROTECT WORKERS IN OXYGEN-DEFICIENCY ATMOSPHERES. RTECS #:9999999ZZ Ingred Name:VENT: PREF BECAUSE IT CAN CTL EMISSIONS OF CONTAMINANT AT ITS SOURCE, PREVENTING DISPERSION OF IT INTO GEN WORK (ING 15) RTECS #:9999999ZZ Ingred Name:ING 14: AREA. PLEASE REFER TO ACGIH DOCUMENT, INDUS VENT, A MANUAL OF REC PRACTICES, MOST RECENT EDITION, FOR DETAILS. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL RAT): 3310 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHAL: CONCENTRATED VAPS MAY CAUSE SERIOUS DMG TO LINING OF NOSE, THROAT, & LUNGS. BRTHG DFCLTYS MAY OCCUR. NEITHER ODOR NOR DEGREE OF IRRIT ARE ADEQ TO INDICATE VAP CONC. INGEST: CAN CAUSE SEV INJURY LEADING TO DEATH. SYMPS INCL SORE THROAT, VOMIT, & DIARR. INGEST OF AS LITTLE AS 1.0 ML HAS (EFTS OF OVEREXP) Explanation of Carcinogenicity:NOT RELEVANT. Effects of Overexposure:HLTH HAZ: RESULTED IN PERFORATION OF ESOPHAGUS. SKIN: CONCENTRATED SOLUTION MAY CAUSE SERIOUS DMG. EFTS MAY INCL REDNESS, PAIN, BURNS. HIGH VAP CONCS MAY CAUSE SENSIT. EYES: CONCENTRATED SOLUTIONS MAY CAUSE SEV DMG FOLLOWED BY LOSS OF SIGHT. EXPOS TO VAP MAY CAUSE INTENSE WATERING & IRRIT. (ING 2) Medical Cond Aggravated by Exposure:PERSONS WITH PREEXISTING SKIN DISORDERS OR EYE PROBLEMS, OR IMPAIRED RESPIRATORY FUNCTION MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THE SUBSTANCE. ======================= First Aid Measures ======================= First Aid:INHAL: REMOVE TO FRESH AIR. IF NOT BRTHG, GIVE ARTIFICIAL RESP. IF BRTHG IS DIFFICULT, GIVE OXYGEN. CALL MD. INGEST: DO NOT INDUCE VOMIT! GIVE LARGE QUANTITIES OF WATER/MILK IF AVAILABLE. NEVER GIVE A NYTHING BY MOUTH TO AN UNCON PERSON. GET MED ATTN IMMED. SKIN: IMMED FLUSH W/PLENTY OF WATER FOR AT LEAST 15 MIN WHILE REMOVING CONTAM CLTHG & SHOES. WASH CLTHG BEFORE REUSE. CALL MD. (ING 4) ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:104F,40C Lower Limits:4.0% Upper Limits:16.0% Extinguishing Media:WATER, DRY CHEMICAL, FOAM OR CARBON DIOXIDE. WATER SPRAY MAY BE USED TO KEEP FIRE-EXPOSED CONTAINERS COOL. Fire Fighting Procedures:WEAR NIOSH APPRVD SCBA & FULL PROT EQUIP . WATER MAY BE USED TO FLUSH SPILLS AWAY FROM EXPOS & TO DILUTE SPILLS TO NON-FLAM MIXTS. WATER-DILUTED (SUP DAT) Unusual Fire/Explosion Hazard:ABOVE FLASH POINT, VAP-AIR MIXTS ARE EXPLO W/IN FLAM LIMS NOTED ABOVE. VAPS CAN FLOW ALONG SURFS TO DISTANT IGNIT SOURCE & FLASH BACK. CONT W/STRONG (SUP DAT) ================== Accidental Release Measures ================== Spill Release Procedures:VENT AREA. REMOVE ALL SOURCES OF IGNIT. WEAR APPROP PERS PROT EQUIP. ISOLATE HAZ AREA. KEEP UNNEC & UNPROT PERS FROM ENTERING. USE WATER SPRAY TO DILUTE SPILL TO NON-FLAM MIXT. CONTAIN & RECOVER W/INE RT MATL (VERMICULITE, DRY SAND, EARTH),(ING 6) Neutralizing Agent:JT BAKER NEUTRASORB(TM) OR TEAM(M) 'LOW NA+' ACID NEUTRALIZERS ARE RECOMMENDED. ====================== Handling and Storage ====================== Handling and Storage Precautions:PROTECT AGAINST PHYSICAL DMG. STORE IN COOL, DRY, WELL-VENTD LOCATION, AWAY FROM ANY AREA WHERE FIRE HAZ MAY BE ACUTE. OUTSIDE/DETACHED STOR IS PREF. Other Precautions:SEPARATE FROM INCOMPATIBLES. CONTRS SHOULD BE BONDED & GROUNDED FOR TRANSFERS TO AVOID STATIC SPARKS. STOR & USE AREAS SHOULD BE NO SMOKING AREAS. USE NON-SPARKING TYPE TOOLS & EQUIP, INCL EXPLO-PROOF VENT. PROTECT FROM FREEZING. (ING 10) ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOS LIM IS EXCEEDED, A NIOSH APPRVD FULL FACEPIECE RESP W/ORG VAP CARTRIDGE MAY BE WORN UP TO 50 TIMES EXPOS LIM/MAX USE CONC SPECIFIED BY APPROP REGULATORY AGENCY/RESP SUPPLIER, WHICHEVER IS LOW EST. FOR EMER/INSTANCES WHERE (ING 12) Ventilation:A SYS OF LOC &/OR GEN EXHST IS REC TO KEEP EMPLOYEE EXPOS BELOW AIRBORNE EXPOS LIMITS. LOC EXHST VENT IS GEN (ING 14) Protective Gloves:IMPERVIOUS GLOVES. Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES . Other Protective Equipment:ANSI APPRVD EMER EYEWASH & DELUGE SHOWER . WEAR IMPERVIOUS PROT CLOTHING, INCL BOOTS, LAB COAT, APRON/COVERALLS. Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER. Supplemental Safety and Health PH: 2.4 (1.0M SOLN). FIRE FIGHT PROC: ACID CAN REACT W/METALS TO FORM HYDROGEN GAS. EXPLO HAZ: OXIDIZERS MAY CAUSE FIRE. REACTS W/MOST METALS TO PRDCE HYDROGEN GAS, WHICH CAN FORM EXPLO MIXT W/AIR. FL AM LIQ & VAP! CNDTNS TO AVOID: FREEZINGWHICH MAY CAUSE CONTR TO BURST. MATLS TO AVOID: HYDROXIDES, OXIDES, PHOSPHATES. ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:244F,118C Melt/Freeze Pt:M.P/F.P Text:63.0F,17.2C Vapor Pres:11 @ 20C Vapor Density:2.1 pH:SUPDAT Evaporation Rate & Reference:0.97 (BUTYL ACETATE=1) Solubility in Water:INFINITELY SOLUBLE Appearance and Odor:CLEAR, COLORLESS LIQUID, WITH STRONG, VINEGAR-LIKE ODOR Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES OXIDIZERS, MOST METALS, CHROMIC ACID, SODIUM PEROXIDE, NITRIC ACID, STRONG CAUSTICS, HEAT, FLAME, CARBONATES, (SUP DAT) Stability Condition to Avoid:HEAT, SUNLIGHT, WATER, FLAME, IGNIT SOURCES, FREEZING, INCOMPATIBLES. ACETIC ACID CONTRACTS SLIGHTLY UPON (SUP DAT) Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE MAY FORM WHEN HEATED TO DECOMPOSITION. MAY ALSO RELEASE TOXIC AND IRRITATING VAPORS. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING SHOULD BE HANDLED AS HAZ WASTE & SENT TO RCRA APPRVD WASTE FACILITY. PROCESSING, USE/CONTAM OF THIS PROD MAY CHANGE WASTE MANAGEMENT OPTIONS. STATE & LO C DISP REGS MAY DIFFER FROM FED REGS. (ING 9) Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.