FISHER SCIENTIFIC -- SODIUM THIOSULFATE SOLUTIONS 0.025N TO 1N, S78930-5 -- 6810-00N091254
===================== Product Identification ===================== Product ID:SODIUM THIOSULFATE SOLUTIONS 0.025N TO 1N, S78930-5 MSDS Date:12/03/1997 FSC:6810 NIIN:00N091254 Status Code:A === Responsible Party === Company Name:FISHER SCIENTIFIC Address:1 REAGENT LANE City:FAIRLAWN State:NJ ZIP:07410 Country:US Info Phone Num:201-796-7100 Emergency Phone Num:201-796-7100 Resp. Party Other MSDS Num.:40182; ACC40182 SS3681 REV. #5 Chemtrec Ind/Phone:(800)424-9300 CAGE:1B464 === Contractor Identification === Company Name:FISHER SCIENTIFIC CO. CHEMICAL MFG DIV Address:1 REAGENT LANE Box:City:FAIRLAWN State:NJ ZIP:07410-2802 Country:US Phone:201-796-7100 CAGE:1B464 ============= Composition/Information on Ingredients ============= Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Minumum % Wt:76.8 Maxumum % Wt:99. Other REC Limits:N/K OSHA PEL:N/K OSHA STEL:N/K ACGIH TLV:N/K ACGIH STEL:N/K Ingred Name:SODIUM THIOSULFATE PENTAHYDRATE CAS:10102-17-7 RTECS #:WE6660000 Minumum % Wt:.6 Maxumum % Wt:22.9 Other REC Limits:N/K OSHA PEL:N/K OSHA STEL:N/K ACGIH TLV:N/K ACGIH STEL:N/K Ingred Name:TETRASODIUM ETHYLENEDIAMINETETRAACETATE DIHYDRATE; (TETRASODIUM ETHYLENE DIAMINE TRETRAACETATE DIHYDRATE) CAS:10378-23-1 = Wt:.27 Other REC Limits:N/K OSHA PEL:N/K OSHA STEL:N/K ACGIH TLV:N/K ACGIH STEL:N/K ===================== Hazards Identification ===================== LD50 LC50 Mixture:SEE TOXICOLOGICAL INFORMATION. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS: NONE. ACUTE: EYES: MAY CAUSE MILD IRRITATION. SKIN: MAY CAUSE IRRITATION. INGESTION: INGESTION OF LARGE AMOUNTS MAY CAUSE GASTROINTESTINAL IRRITATION. INHALATION: LOW HAZARD FOR USUAL I NDUSTRIAL HANDLING. MAY CAUSE RESPIRATORY TRACT IRRITATION. CHRONIC: NO INFORMATION FOUND. Effects of Overexposure:SEE HEALTH HAZARDS. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, OCCASIONALLY LIFTING THE UPPER AND LOWER LIDS. GET MEDICAL AID. SKIN: FLUSH WITH PLENTY OF SOAP AND WATER FOR AT LEAST 15 MINUTES WHILE REMOVI NG CONTAMINATED CLOTHING AND SHOES. GET MEDICAL AID IF IRRITATION DEVELOPS OR PERSISTS. INGESTION: IF VICTIM IS CONSCIOUS AND ALERT, GIVE 2-4 CUPFULS OF MILK OR WATER. GET MEDICAL AID. INHALATION: REM OVE FROM EXPOSURE TO FRESH AIR IMMEDIATELY. IF NOT BREATHING, GIVE ARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICAL AID. NOTES TO MD: TREAT SYMPTOMATICALLY AND SUPPORTIVELY. ANTIDOTE: NONE REPORTED. ===================== Fire Fighting Measures ===================== Extinguishing Media:FOR SMALL FIRES, USE WATER SPRAY, DRY CHEMICAL, CARBON DIOXIDE OR CHEMICAL FOAM. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NFPA RATINGS: NOT PUBLISHED. ================== Accidental Release Measures ================== Spill Release Procedures:USE PROPER PERSONAL PROTECTIVE EQUIPMENT AS INDICATED IN CONTROL MEASURES SECTION. ABSORB SPILL WITH INERT MATERIAL (E.G., DRY SAND OR EARTH), THEN PLACE INTO A CHEMICAL WASTE CONTAINER. ====================== Handling and Storage ====================== Handling and Storage Precautions:AVOID PROLONGED OR REPEATED CONTACT WITH SKIN. AVOID INGESTION AND INHALATION. USE WITH ADEQUATE VENTILATION. Other Precautions:STORE IN A COOL, DRY PLACE. STORE IN A TIGHTLY CLOSED CONTAINER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:FOLLOW THE OSHA RESPIRATOR REGULATIONS FOUND IN 29 CFR 1910.134 OR EUROPEAN STANDARD EN 149. ALWAYS USE A NIOSH OR EUROPEAN STANDARD EN 149 APPROVED RESPIRATOR WHEN NECESSARY. Ventilation:USE ADEQUATE VENTILATION TO KEEP AIRBORNE CONCENTRATIONS LOW. Protective Gloves:WEAR IMPERVIOUS GLOVES . Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . (SUP DAT) Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE SHOWER . WEAR APPROPRIATE PROTECTIVE CLOTHING TO PREVENT SKIN EXPOSURE. Supplemental Safety and Health EYE PROTECTION: WEAR APPROPRIATE PROTECTIVE EYEGLASSES OR CHEMICAL SAFETY GOGGLES AS DESCRIBED BY OSHA'S EYE AND FACE PROTECTION REGULATIONS IN 29 CFR 1910.133 OR EUROPEAN STANDARD EN166. ================== Physical/Chemical Properties ================== Boiling Pt:=100.C, 212.F Melt/Freeze Pt:=0.C, 32.F Vapor Pres:14 MM HG Spec Gravity:1.0-1.1 Evaporation Rate & Reference:>1 (ETHER=1) Solubility in Water:COMPLETELY SOLUBLE Appearance and Odor:COLORLESS LIQUID WITH NO ODOR REPORTED. ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES SODIUM THIOSULFATE VIOLENTLY REACTS WITH SODIUM NITRILE. IT IS ALSO INCOMPATIBLE WITH STRONG OXIDIZERS, ACIDS. Stability Condition to Avoid:ACIDS, STRONG OXIDANTS. Hazardous Decomposition Products:HYDROGEN SULFIDE, SODIUM OXIDE. =================== Toxicological Information =================== Toxicological Information:RTECS: CAS # 7732-18-5: ZC0110000; CAS # 10102-17-7: WE6660000; CAS # 10378-23-1: UNLISTED. LD50/LC50: CAS # 7732-18-5: ORAL, RAT: LD50 = >90 ML/KG; CAS # 10102-17-7: ORAL, MOUSE: LD50 = 2700 MG/KG. E PIDEMIOLOGY/TERATOGENICITY/REPRODUCTIVE EFFECTS/NEUROTOXICITY/MUTAGENICITY/OTHER STUDIES: NO DATA AVAILABLE. ===================== Ecological Information ===================== Ecological:ECOTOXICITY: NOT AVAIL. ENVIRONMENTAL FATE: NOT AVAIL. PHYSICAL/CHEM: NOT AVAIL. OTHER: NOT AVAIL. OTHER INFO: WGK (WATER DANGER/PROT): CAS # 7732-18-5: NO INFO AVAIL; CAS # 10102-17-7: 0; CAS # 10378 -23-1: NO INFO AVAIL. CANADA: CAS # 7732-18-5 IS LISTED ON CANADA'S DSL/NDSL LIST; THIS PROD HAS A WHMIS CLASSIFICATION OF NOT CONTROLLED. NONE OF THE INGS ARE LISTED ON CANADA'S ING DISCLOSURE LIST. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN A MANNER CONSISTENT WITH FEDERAL, STATE, AND LOCAL REGULATIONS. RCRA D-SERIES MAXIMUM CONCENTRATION OF CONTAMINANTS: NONE LISTED. RCRA D-SERIES CHRONIC TOXICITY REFERENCE LEVELS: NONE LI STED. RCRA F-SERIES: NONE LISTED. RCRA P-SERIES: NONE LISTED. RCRA U-SERIES: NONE LISTED. =================== MSDS Transport Information =================== Transport Information:US DOT: NO INFORMATION AVAILABLE. IMO: NO INFORMATION AVAILABLE. IATA: NO INFORMATION AVAILABLE. RID/ADR: NO INFORMATION AVAILABLE. CANADIAN TOG: NO INFORMATION AVAILABLE. ===================== Regulatory Information ===================== SARA Title III Information:SECTION 302 (RQ): NONE OF THE CHEMICALS IN THIS MATERIAL HAVE AN RQ. SECTION 302 (TPQ): NONE OF THE CHEMICALS IN THIS PRODUCT HAVE A TPQ. SECTION 313: NO CHEMICALS ARE REPORTABLE UNDER SECTION 313. Federal Regulatory Information:US FED: TSCA: CAS # 7732-18-5 IS LISTED ON TSCA INVENTORY; CAS # 10102-17-7 IS NOT ON TSCA INVENTORY. IT IS A HYDRATE & EXEMPT FROM TSCA INVENTORY REQS (40 CFR 720.3(0)(2)); CAS # 10378-23-1 IS NOT LI STED ON TSCA INVENTORY. IT IS FOR RESEARCH & DEVEL USE ONLY. NONE OF THE CHEMS ARE ON HLTH & SFTY REPORTING LIST. NONE OF THE CHEMS ARE UNDER A CHEM TEST RULE. NONE OF THE CHEMS ARE LISTED UNDER TSCA SECTION 12B. NONE OF THE CHEMS HAVE A SNUR (SIGNIFICANT NEW USE RULE) UNDER TSCA. CLEAN AIR ACT: THI S MATL DOES NOT CONTAIN ANY HAZ AIR POLLUTANTS, ANY CLASS 1 OZONE DEPLETORS, ANY CLASS 2 OZONE DEPLETORS. (OTHER INFO) State Regulatory Information:WATER IS NOT PRESENT ON STATE LISTS FROM CA, PA, MN, MA, FL, OR NJ. SODIUM THIOSULFATE, PENTAHYDRATE IS NOT PRESENT ON STATE LISTS FROM CA, PA, MN, MA, FL, OR NJ. TETRASODIUM ETHYLENE DIAMINE TETRAACE TATE DIHYDRATE IS NOT PRESENT ON STATE LISTS FROM CA, PA, MN, MA, LF, OR NJ. CALIFORNIA NO SIGNIFICANT RISK LEVEL: NONE OF THE CHEMICALS IN THIS PRODUCT ARE LISTED. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.